Synthesis, characterization and electrochemical studies of nanosized Barium Cerate

Document Type : Research Article

Authors

Department of Chemistry, Vijayanagara Sri Krishnadevaraya University, Ballari, Karnataka, India.

10.22034/crl.2024.450392.1317
Abstract
Nano sized bimetallic oxide materials have been extensively studied worldwide because of their unique properties such as electrical conductivity, magnetic property and superior mechanical properties. The exercise objects the synthesis, characterization and studies like thermal and electrochemical study of the barium cerate (BaCeO3). The facial approach to preparing well dispersed nanocrystals of (BaCeO3) was prepared by oxalate precursor method. Barium oxalate and cerium oxalate precursors were prepared by direct dispersion of barium and cerium salt into oxalic acid solution separately. These precursors are undertaken for self-propagating combustion reaction under the influence of polyvinyl alcohol (PVA) fuel in the weight ration 1:1:5 to form BaCeO3 as required product. X-Ray diffraction (XRD) tool which is used to study the structural confirmation of prepared bimetallic oxide nanomaterials sample. The presence of a 100% peak (110) along with other reflections in the pattern confirms the sample. Morphological study of the sample was carried out by scanning electron microscope (SEM) tool. Bonding nature of the sample was well studied by Fourier transfer infrared (FT-IR) instrumentation. Metal confirmation in the prepared sample was identified by EDX analysis. Absorption variation was well analyzed by UV-Vis spectroscopy. Maximum absorption band at 425 nm signifies the sample phase. Raman spectroscopic (RS) study was undertaken to view its structural organization. Dynamic light scattering (DLS) study was implemented to know the size of the sample. Cyclic voltammetry (CV) and thermal gravimetric analysis (TGA) studies are also experimented to know the electrolytic and thermal behavior of the barium cerate sample. Complete decomposition of the sample takes place at 779.41oC records thermal stability.

Keywords

Subjects


[1] (a) W. Xu, D. Guo, A.G. Ebadi, M. Toughani, E. Vessally, Transition-metal catalyzed carboxylation of organoboron compounds with CO2. J. CO2 Util., 45 (2021) 101403; (b) L. Hao, G. Ding, D.A. Deming, Q. Zhang, Recent advances in green synthesis of functionalized phenols from aromatic boronic compounds. Eur. J. Org. Chem, (2019) 7307-7321; (c) F. Behmagham, M.A. Mustafa, S.K. Saraswat, K.A. Khalaf, M. Kaur, P. Ghildiyal, E. Vessally, Recent investigations into deborylative (thio-/seleno-) cyanation of aryl boronic acids. RSC Adv., 14 (2024) 9184-9199; (d) M. R. J. Sarvestani, N. Mert, E. Vessally, Cross-dehydrogenative coupling of aldehydes with N-hydroxyimides: An efficient and straightforward route to N-hydroxyimides esters, J. Chem. Lett. 1 (2020) 93-102. 10.22034/jchemlett.2020.120304; (e) J. Khayitov et. al, Transition metal-catalyzed carbonylative coupling of aryl/alkyl halides with thiols: A straightforward, Chem. Rev. Lett. 7 (2024) 333-345. 10.22034/crl.2024.448261.1311; (f) E. A. Mahmood, B. Azizi, S. Majedi, Decarboxylative cyanation and azidation of carboxylic acids: An overview, Chem. Rev. Lett. 3 (2020) 2-8. 10.22034/crl.2020.219565.1036.
[2] A.J. Lennox, G.C. Lloyd-Jones, Selection of boron reagents for Suzuki–Miyaura coupling. Chem. Soc. Rev., 43 (2014) 412-443.
[3] G.F.S. Fernandes, W.A. Denny, J.L. Dos Santos, Boron in drug design: Recent advances in the development of new therapeutic agents. Eur. J. Med. Chem., 179 (2019) 791-804.
[4] J. Plescia, N. Moitessier, Design and discovery of boronic acid drugs. Eur. J. Med. Chem., 195 (2020) 112270.
[5] M.P. Silva, L. Saraiva, M. Pinto, M.E. Sousa, Boronic acids and their derivatives in medicinal chemistry: synthesis and biological applications. Molecules, 25 (2020) 4323.
[6] (a) T. Zhang, X. Chen, C. Xiao, X. Zhuang, X. Chen, Synthesis of a phenylboronic ester-linked PEG-lipid conjugate for ROS-responsive drug delivery. Polym. Chem., 8 (2017) 6209-6216; (b) Y. Zhang, P. He, X. Liu, H. Yang, H. Zhang, C. Xiao, X. Chen, A PEGylated alternating copolymer with oxidation-sensitive phenylboronic ester pendants for anticancer drug delivery. Biomater. Sci., 7 (2019) 3898-3905.
[7] W.K. Chow, O.Y. Yuen, P.Y. Choy, C.M. So, C.P. Lau, W.T. Wong, F.Y. Kwong, A decade advancement of transition metal-catalyzed borylation of aryl halides and sulfonates. RSC Adv., 3 (2013) 12518-12539.
[8] (a) L. Xu, G. Wang, S. Zhang, H. Wang, L. Wang, L. Liu, J. Jiao, P. Li, Recent advances in catalytic C− H borylation reactions. Tetrahedron, 73 (2017) 7123-7157; (b) Y.M. Tian, X.N. Guo, H. Braunschweig, U. Radius, T.B. Marder, Photoinduced borylation for the synthesis of organoboron compounds: focus review. Chem. Rev., 121 (2021) 3561-3597; (c) S. Daliran, A.R. Oveisi, Y. Peng, A. López-Magano, M. Khajeh, et. al, Metal–organic framework (MOF)- covalent-organic framework (COF)-, and porous-organic polymers (POP)-catalyzed selective C–H bond activation and functionalization reactions, Chem. Soc. Rev. 51 (2022)7810-7882.
[9] (a) L. Wang, W. He, Z. Yu, Transition-metal mediated carbon–sulfur bond activation and transformations. Chem. Soc. Rev., 42 (2013) 599-621; (b) J. Lou, Q. Wang, P. Wu, H. Wang, Y.G. Zhou, Z. Yu, Transition-metal mediated carbon–sulfur bond activation and transformations: an update. Chem. Soc. Rev., 49 (2020) 4307-4359; (c) J. Corpas, S.H. Kim-Lee, P. Mauleón, R.G. Arrayás, J.C. Carretero, Beyond classical sulfone chemistry: metal-and photocatalytic approaches for C–S bond functionalization of sulfones. Chem. Soc. Rev., 51 (2022) 6774-6823; (d) K. Yang, Q. Li, Z.Y. Li, X. Sun, Transition-metal-free C–S bond cleavage and transformation of organosulfur compounds. Chemical Communications. Chem. Commun., 59 (2023) 5343-5364.
[10] A. K. O. Aldulaimi, A. H. Hussein, M. J. Mohammed, H. R. Saud, H. Bahair, F. Shahimi, Direct hydroxyazidation of alkenes: A viable strategy for the synthesis of β-azido alcohols, . Chem. Rev. Lett. 7 (2024) 53-64.10.22034/crl.2024.430494.1270
[11] (a) .C. Y. Hsu, A. K. O. Aldulaimi, H. Bahair, A. H. Adhab, S. K. Saraswat, Hydrazinosulfonylation of aryl electrophiles: a straightforward approach for the synthesis of aryl N-aminosulfonamides, RSC adv. 13(27) (2023) 18546-18560; (b) A. K. Obaid Aldulaimi; E. A. Mahmood; E. Vessally, Sulfaguanidines: A new class of carbonic anhydrase inhibitors, Med Med Chem, 1 (2024) 2-9. 10.22034/medmedchem.2024.198914
[12] Y. Uetake, T. Niwa, T. Hosoya, Rhodium-catalyzed ipso-borylation of alkylthioarenes via C–S bond cleavage. Org. Lett., 18 (2016) 2758-2761.
[13] M. Bhanuchandra, A. Baralle, S. Otsuka, K. Nogi, H. Yorimitsu, A. Osuka, Palladium-catalyzed ipso-borylation of aryl sulfides with diborons. Org. Lett., 18 (2016) 2966-2969.
[14] J. Zeng, M. Naito, T. Torigoe, M. Yamanaka, Y. Kuninobu, Iridium-catalyzed ortho-C–H borylation of thioanisole derivatives using bipyridine-type ligand. Org. Lett., 22 (2020) 3485-3489.
[15] E. Pietrasiak, S. Ha, S. Jeon, J. Jeong, J. Lee, J. Seo, E. Lee, Cobalt-catalyzed formation of Grignard reagents via C–O or C–S bond activation. J. Org. Chem., 87 (2022) 8380-8389.
[16] H. Minami, S. Otsuka, K. Nogi, H. Yorimitsu, Palladium-catalyzed borylation of aryl sulfoniums with diborons. ACS Catal., 8 (2018) 579-583.
[17] C. Huang, J. Feng, R. Ma, S. Fang, T. Lu, W. Tang, D. Du, J. Gao, Redox-neutral borylation of aryl sulfonium salts via C–S activation enabled by light. Org. Lett., 21 (2019) 9688-9692.
[18] J. Wu, Z. Wang, X.Y. Chen, Y. Wu, D. Wang, Q. Peng, P. Wang, Para-selective borylation of monosubstituted benzenes using a transient mediator. Sci. China Chem., 63 (2020) 336-340.
[19] F. Berger, M.B. Plutschack, J. Riegger, W. Yu, S. Speicher, M. Ho, N. Frank, T. Ritter, Site-selective and versatile aromatic C−H functionalization by thianthrenation. Nature, 567 (2019) 223-228.
[20] B. Li, K. Wang, H. Yue, A. Drichel, J. Lin, Z. Su, M. Rueping, Catalyst-free C(sp2)-H borylation through aryl radical generation from thiophenium salts via electron donor–acceptor complex formation. Org. Lett., 24 (2022) 7434-7439.
[21] D. Qiu, S. Li, G. Yue, J. Mao, B. Xu, X. Yuan, F. Ye, Synthesis of arylboronates via the Pd-catalyzed desulfitative coupling reaction of sodium arylsulfinates with bis(pinacolato) diboron. Tetrahedron Lett., 85 (2021) 153478.
[22] T. Shimada, Y.H. Cho, T. Hayashi, Nickel-catalyzed asymmetric grignard cross-coupling of dinaphthothiophene giving axially chiral 1,1'-binaphthyls. J. Am. Chem. Soc., 124 (2002) 13396-13397.
[23] H. Saito, K. Nogi, H. Yorimitsu, Palladium-catalyzed double borylation of diaryl sulfoxides with diboron. Synthesis, 49 (2017) 4769-4774.
[24] M. Huang, Z. Wu, J. Krebs, A. Friedrich, X. Luo, S.A. Westcott, U. Radius, T.B. Marder, Ni‐catalyzed borylation of aryl sulfoxides. Chem. Eur. J., 27 (2021) 8149-8158.
[25] S. Wang, H. Wang, B. König, Photo-induced thiolate catalytic activation of inert Caryl-hetero bonds for radical borylation. Chem, 7 (2021) 1653-1665.
[26] Y. Maekawa, Z.T. Ariki, M. Nambo, C.M. Crudden, Pyridine-catalyzed desulfonative borylation of benzyl sulfones. Org. Biomol. Chem., 17 (2019) 7300-7303.
[27] M. Huang, J. Hu, I. Krummenacher, A. Friedrich, H. Braunschweig, S.A. Westcott, U. Radius, T.B. Marder, Base‐mediated radical borylation of alkyl sulfones. Chem. Eur. J., 28 (2022) 202103866.
[28] M. Huang, M. Tang, J. Hu, S.A. Westcott, U. Radius, T.B. Marder, Cu-mediated vs. Cu-free selective borylation of aryl alkyl sulfones. Chem. Commun., 58 (2022) 395-398.
[29] L. Tang, G. Lv, F. Jia, R. Zhao, X. Wang, Q. Zhou, Visible light‐driven eosin Y‐catalyzed Suzuki‐type sulfonylation. Adv. Synth. Catal., 366 (2024) 70-76.
[30] H. Saito, K. Nogi, H. Yorimitsu, Rh/Cu-cocatalyzed ring-opening diborylation of dibenzothiophenes for aromatic metamorphosis via diborylbiaryls. Chem. Lett., 46 (2017) 1122-1125.
[31] A. Kaga, H. Iida, S. Tsuchiya, H. Saito, K. Nakano, H. Yorimitsu, Aromatic metamorphosis of thiophenes by means of desulfurative dilithiation. Chem. Eur. J., 27 (2021) 4567-4572.
Volume 7, Issue 3 - Serial Number 3
March and April 2024
Pages 425-432

  • Receive Date 29 March 2024
  • Revise Date 09 May 2024
  • Accept Date 14 June 2024