Bis[(2-ethoxy-2-oxoethyl)triphenyl phosphonium] di-µ-chloro-bis[bromochloro palladate (II)] and its application in Heck and Suzuki cross-coupling reactions

Document Type : Research Article

Authors

1 Department of Chemistry, Faculty of science, Ilam University, Ilam, Ilam 69315-516, Iran.

2 Department of Chemistry, Faculty of Science, Ilam University, Ilam, Iran.

3 Department of Animal Science, Faculty of Agriculture, Ilam University, Ilam- Iran

4 Department of Animal Science, Faculty of Agriculture, Ilam University, Ilam- Iran.

Abstract

In this study, the phosphonium salt [Ph3PCHC(O)OCH2CH3]Br undergoes a reaction with palladium(II) chloride, resulting in the formation of [Ph3PCHC(O)OCH2CH3]2[Pd2Cl4Br2]. The synthesized compound underwent thorough characterization through elemental analysis, as well as FT-IR, 1H, 31P, and 13C NMR spectroscopies. The investigation revealed that this particular substance serves as an efficient catalyst for the Heck cross-coupling reaction, leading to the synthesis of diverse unsaturated products with highly favorable outcomes. Moreover, it has demonstrated effectiveness in catalyzing the Suzuki cross-coupling reaction. Notably, the catalyst exhibits sustained catalytic activity and can be conveniently recovered and reused.

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Chemical Review and Letters
Volume 7, Issue 2 - Serial Number 2
March 2024
Pages 211-221

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History

  • Receive Date: 08 January 2024
  • Revise Date: 03 February 2024
  • Accept Date: 03 February 2024

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